Innovative GaN Nanowire Architecture for Efficient and Stable Photoelectrochemical Hydrogen Generation
Key Ideas
- Photoelectrochemical water splitting using GaN nanowire-on-Si wafer architecture offers a highly efficient and stable pathway for hydrogen production.
- The GaN nanowires, with tailored facets and loaded with Au nanoparticles, show high onset potential and stability in PEC hydrogen evolution.
- The reconfigured GaN nanowire/Au heterointerface enhances adsorption energy, preventing Au nanoparticle detachment and optimizing hydrogen adsorption for active interfacial regions.
The article discusses the development of a novel gallium-nitride (GaN) semiconductor in the form of a nanowire array grown on a silicon substrate for efficient photoelectrochemical (PEC) water splitting to generate hydrogen. By tailoring the GaN nanowires through a selective chemical-etching step and loading them with Au nanoparticles as cocatalysts, the constructed Au/Faceted-GaN/Si photocathodes demonstrate high performance with an onset potential of 0.52 V vs. RHE and a large applied bias photon-to-current efficiency of 10.36% under solar illumination. The study showcases a one-dimension on three-dimension (1D/3D) configured photoelectrode architecture that achieves both high efficiency and stability in PEC hydrogen evolution for over 800 hours. The innovative approach involves facet-induced strong electronic interactions at the GaN/Au interface, forming a reconfigured GaN nanowire/Au heterointerface that enhances stability and catalytic activity. This strategy provides a promising platform for future advanced hydrogen production. The research represents a significant step towards sustainable hydrogen fuel generation through a renewable and environmentally friendly process.
Topics
Production
Renewable Energy
Clean Energy
Stability
Nanotechnology
Photoelectrochemical
Semiconductor Materials
Catalytic Activity
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