Unveiling the Atomic Vandal: A Breakthrough in Platinum Corrosion
Key Ideas
  • Scientists from Leiden University and SLAC National Laboratory discovered the cause of rapid platinum electrode corrosion, crucial for green hydrogen production.
  • Platinum electrodes, critical in electrolysers, degrade under negative polarisation due to platinum hydrides, not platinides as previously thought.
  • Advanced X-ray spectroscopy at SLAC allowed researchers to observe platinum corrosion in real-time, confirming platinum hydrides as the primary cause.
  • This breakthrough enables the development of solutions for platinum corrosion, advancing the field of electrochemical devices and enhancing green hydrogen production.
Scientists from Leiden University and the Department of Energy’s SLAC National Laboratory have made a significant breakthrough in understanding the rapid corrosion of platinum electrodes. The mystery behind platinum's degradation under negative polarization has been unraveled, pointing to the formation of platinum hydrides rather than platinides as previously believed. The research team utilized high-energy-resolution X-ray spectroscopy techniques at SLAC's Stanford Synchrotron Radiation Lightsource to observe platinum corrosion as it occurred in an electrolyte. By studying the X-ray spectra from the corroding platinum electrode, the researchers confirmed that platinum hydrides were responsible for the degradation. Through computational models and advanced X-ray science, the team demonstrated that platinum hydride formation was the key factor leading to the electrode's breakdown. This discovery opens new avenues for addressing platinum corrosion in electrolysers and other electrochemical devices, offering insights that can enhance green hydrogen production and sensor reliability. The project highlights the importance of collaborative expertise in scientific research and showcases the power of cutting-edge techniques in solving longstanding scientific questions. By advancing the understanding of platinum corrosion mechanisms, this breakthrough holds promise for the development of more affordable and sustainable hydrogen production methods.
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