Breakthrough in Fuel Cell Technology: High Proton Conductivity Material Discovered in Tokyo
Key Ideas
  • Researchers from Tokyo Tech identified Ba5R2Al2SnO13 oxides as materials with high proton conductivity and thermal stability, suitable for next-gen fuel cells.
  • The hexagonal perovskite-related oxide demonstrated a high proton conductivity of 0.01 S cm⁻¹ at 303 °C and exceptional chemical stability under operating conditions.
  • The material's unique crystal structure allows full hydration, fast proton migration, and long-range proton diffusion, enabling efficient and durable fuel cells at lower temperatures.
  • This breakthrough could pave the way for the development of more efficient and environmentally friendly fuel cells for clean energy production.
A recent study led by researchers from Tokyo Tech has unveiled a significant advancement in fuel cell technology by identifying hexagonal perovskite-related Ba5R2Al2SnO13 oxides as exceptional materials for next-generation fuel cells. These materials exhibit high proton conductivity and thermal stability, making them promising candidates for protonic ceramic fuel cells operating at intermediate temperatures without degradation. The study, published in the Journal of the American Chemical Society, showcased the remarkable properties of Ba5R2Al2SnO13 (where R represents rare earth metals). The material demonstrated a high proton conductivity of 0.01 S cm⁻¹ at 303 °C, far surpassing other proton conductors. Through a unique crystal structure allowing full hydration and rapid proton diffusion, the material offers efficient proton migration, leading to enhanced conductivity. Furthermore, the material's chemical stability was confirmed under various operating conditions, highlighting its suitability for continuous operation without degradation. The researchers synthesized Ba5Er2Al2SnO13 using solid-state reactions and observed its exceptional properties, including a fractional water uptake indicating full hydration and a 2,100-fold increase in conductivity in wet conditions. Proton migration pathways were studied in simulations, revealing the material's fast proton diffusion and high proton concentration. Professor Masatomo Yashima emphasized the significance of this discovery, noting that the material's properties could lead to the development of efficient, durable, and lower-temperature fuel cells. Overall, this breakthrough opens new avenues for the advancement of proton conductors and holds promise for the future of clean energy production.
ADVANCEH2

Our vision is to be the world's leading online platform for advancing the use of hydrogen as a critical piece needed to deliver net-zero initiatives and the promise of a clean H2 energy future.

© 2024 AdvanceH2, LLC. All rights reserved.