Innovative Nitrogen-Doped Alloy Catalysts Enhance Durability of Fuel Cells
Key Ideas
- Researchers developed a technology utilizing nitrogen to enhance the durability of platinum-cobalt (PtCo) alloy catalysts, crucial for fuel cells.
- The new nitrogen-doping technique stabilizes cobalt through bonding, addressing cost and durability issues associated with platinum catalysts for fuel cells.
- The technology enables the commercialization of low-platinum, high-stability fuel cells, surpassing US Department of Energy's 2025 durability targets.
- The nitrogen-doped PtCo alloy exhibits exceptional structural stability and performance, showing promise for various sectors including automotive, marine, aviation, and power generation.
Researchers from Daegu Gyeongbuk Institute of Science and Technology have developed a groundbreaking technology that significantly enhances the durability of alloy catalysts in fuel cells. By incorporating nitrogen into PtCo alloys, the team successfully addressed the high cost and low durability issues associated with platinum catalysts, which are essential for Proton Exchange Membrane Fuel Cells (PEMFC) used in environmentally friendly vehicles. The study, published in the Journal of the American Chemical Society, introduces a novel synthesis technique that stabilizes cobalt in the PtCo alloy through cobalt–nitrogen bonding, preventing its dissolution and significantly increasing durability. This advancement paves the way for commercializing fuel cells with reduced platinum usage while maintaining high performance and stability.
The nitrogen-doped PtCo alloy exhibits exceptional structural stability and ordered PtCo structures both inside and on the surface of the alloy. Professor Seoin Baek's computational chemical analyses confirmed that the cobalt–nitrogen bond doubles the dissolution energy of cobalt, enhancing its stability within the alloy. In accelerated durability tests, the alloy outperformed commercial catalysts, exceeding the 2025 durability targets set by the US Department of Energy.
The research aims to enhance fuel cell performance by overcoming the durability limitations of existing alloys, providing a technology that combines longevity and efficiency for hydrogen fuel cells. Professor Jongsung Yu from the Department of Energy Science & Engineering envisions this technology contributing to the widespread adoption of hydrogen fuel cells in various sectors such as automotive, marine, aviation, and power generation. Supported by the National Research Foundation of Korea, this study signifies a significant step towards sustainable energy solutions with hydrogen fuel cells.