Hydrogen, known as a green fuel and essential element in the universe, has faced challenges in production due to the limitations of platinum-based catalysts. The rising demand for high-purity hydrogen has led to the exploration of alternative methods to overcome the barriers posed by the scarcity and high costs of noble metal species. In response to this challenge, organocatalysts have emerged as a promising solution in the industry. These catalysts, devoid of metal components, offer a cost-effective and efficient approach to hydrogen evolution reactions (HER). The designed organocatalysts incorporating nitrogen and phosphorus sites have demonstrated impressive catalytic activity and stability, surpassing traditional platinum-based options. The practical application of organocatalysts has resulted in a significant reduction in the price of hydrogen production, making the transition to a green hydrogen era more feasible for society. Furthermore, the integration of organocatalysts into inorganic electrochemistry signifies a new era of organo-electrocatalysis. This advancement not only revolutionizes hydrogen production but also catalyzes progress in metal-dominated cathodic electrocatalysis and traditional organic catalysis, promising a sustainable future for energy production.