The article provides a comprehensive overview of recent research focusing on the use of various catalysts for sustainable hydrogen production from sodium borohydride. Studies explore the application of nanocatalysts, such as Co/CuFe2O4, for enhancing hydrogen generation through hydrolysis. Additionally, researchers are investigating the catalytic potential of waste materials like poplar sawdust and ceramic frit in triggering sodium borohydride methanolysis reactions. Metal-free catalysts derived from organic waste sources, including spent coffee ground and pomegranate peel, offer new avenues for efficient hydrogen production. The development of bimetallic catalysts and carbon-supported catalysts using agricultural waste aims to improve the efficiency of sodium borohydride methanolysis and electrooxidation processes. These innovations signify significant progress towards sustainable hydrogen generation and highlight the potential of utilizing diverse catalysts for promoting renewable energy sources.