The article discusses a breakthrough in the field of solar water splitting by overcoming performance issues associated with organic photoactive materials. Anodes containing single-junction organic solar cells and Earth-abundant electrocatalysts have been developed to achieve high water oxidation photocurrent density and operational stability lasting for days. Furthermore, the use of tandem devices has enabled unassisted solar water splitting, marking a significant advancement in the production of renewable hydrogen. The research introduces an innovative approach where graphite-protected organic photoactive layers are utilized, promising direct solar hydrogen generation. This development not only enhances solar water oxidation but also offers a sustainable and efficient method for water splitting, contributing to the global shift towards renewable energy sources.